MAGNETOSTRUCTURAL J-CORRELATIONS IN Fe(III) COMPLEXES – A REVISION
Keywords:exchange coupling, X-ray structure, magnetostructural correlation, Fe(III) complexes
The magnetostructural correlations in Fe(III) complexes, originally outlined by Gorun and Lippard has been revised. Other correlation variants have been tested and the dataset enlarged for more recent entries possessing the Fe-O-Fe bridge including dinuclear, tetranuclear and hexanuclear Fe(III) complexes. The resulting relationships confirm that instead of the original suggestions, the correlation could stay as a linear relationship which covers the possibilities of positive values of exchange coupling constants.