TY - JOUR AU - Boča, Roman PY - 2020/12/01 Y2 - 2024/03/29 TI - Thermodynamics and cooperativeness of the spin crossover JF - Nova Biotechnologica et Chimica JA - Nova Biotechnol. Chim. VL - 19 IS - 2 SE - Reviews DO - 10.36547/nbc.v19i2.769 UR - https://journals.scicell.org/index.php/NBC/article/view/769 SP - 138-153 AB - Spin transition – a passage from the low-spin electronic state to the high-spin one of Fe(III) and Fe(II) complexes is assessed from several points of view: theoretical modelling, magnetic susceptibility data, and calorimetric measurements. The concept of the cooperativeness in the solid state is discussed in detail. Thermodynamic parameters are mutually correlated for a set of analogous Fe(III) complexes by using modern statistical methods. ER -