Thermodynamics and cooperativeness of the spin crossover

Authors

  • Roman Boča

DOI:

https://doi.org/10.36547/nbc.v19i2.769

Keywords:

Cooperativeness, Spin crossover, Statistical analysis, Thermodynamic parameters

Abstract

Spin transition – a passage from the low-spin electronic state to the high-spin one of Fe(III) and Fe(II) complexes is assessed from several points of view: theoretical modelling, magnetic susceptibility data, and calorimetric measurements. The concept of the cooperativeness in the solid state is discussed in detail. Thermodynamic parameters are mutually correlated for a set of analogous Fe(III) complexes by using modern statistical methods.

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Published

2020-12-01