Thermodynamics and cooperativeness of the spin crossover

Authors

  • Roman Boča

DOI:

https://doi.org/10.36547/nbc.v19i2.769

Keywords:

Cooperativeness, Spin crossover, Statistical analysis, Thermodynamic parameters

Abstract

Spin transition – a passage from the low-spin electronic state to the high-spin one of Fe(III) and Fe(II) complexes is assessed from several points of view: theoretical modelling, magnetic susceptibility data, and calorimetric measurements. The concept of the cooperativeness in the solid state is discussed in detail. Thermodynamic parameters are mutually correlated for a set of analogous Fe(III) complexes by using modern statistical methods.

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Published

2020-12-01

How to Cite

Boča, R. (2020). Thermodynamics and cooperativeness of the spin crossover. Nova Biotechnologica Et Chimica, 19(2), 138–153. https://doi.org/10.36547/nbc.v19i2.769

Issue

Vol. 19 No. 2 (2020)

Section

Reviews

License

Copyright (c) 2020 Roman Boča

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

All papers published in the Nova Biotechnologica et Chimica (NBC)  are published under a CC-BY licence (CC-BY 4.0). Published materials can be shared (copy and redistribute the material in any medium or format) and adapted (remix, transform, and build upon the material for any purpose, even commercially) with specifying the author(s).